Place-holder, no picture available of Ununoctium
 
    

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Periodic Table

Ground State Electron Configuration of Ununoctium

  2,8,18,32,

  32,18,8  

Phase at Room Temperature: Expected to be a Gas

 

He
2
Ne
10
Ar
18
Kr
36
Xe
54
Rn
86
Uuo
118
Uho
168
Buo
218

Ununoctium  -  Moskowium

SymbolUuo
 should be radioactive 
Atomic Number118
Noble gas
Relative Atomic Mass
12C = 12.0000
[ 294 ]  Uuo atomic weights Herman H. Rosenfeld
Significant Atomic Mass314
Neutrons  196
Atomic Radius  pm< 152 >
First Ionisation Energy
kJ mol -1
< 963 >
Ionization energy (eV)< 9.9599 >
Electronegativity-
Density  kg m -3< 13.65 >
Molar Volume   cm 3< 62.58 >
Thermal Conductivity
W m -1 K -1
< 0.001807 >
Melting Point  °C -30,3 °C,   < 243K >
Boiling Point  °C -22,6 °C,   < 250K >
Phase at Room TemperatureExpected to be a 
colourless gas
Number of Isotopes4 ?
Isotopes of superheavy elements293 Uuo  12 µs  ?
294 Uuo  0.89 ms /1.8x10-3 s
295 Uuo  ?
297 Uuo  ?
 
(unconfirmed)
Inner + outer Shells
  4  
+
  3  
 = 7
Inner + outer Orbitals
  60  
+
  58  
 = 118
Filling Orbital
  7p 6 
Ground State Electron Configuration
[Rn]  5f 14  6d 10    7p 6 = [Uuo]
Ground State Electron Configuration with 
free Orbitals (n=0)

 

  0,0,0,0,0,0,0  
Ground State Electron Configuration with free Orbitals of Ununoctium

Ground State Electron Configuration with compressed Orbitals  (n=162)

 

  0,0,0,0,18,54,90   

 

Ground State Electron Configuration with compressed Orbitals of Ununoctium
 
Singularity
280
60
+
58
+
0
+
162
 
 spd fghij
12       
226      
32610     
4261014    
526101418   
62610141822  
7261014182226 
8        
 
 Term Symbol1S 0
 CAS Reg-ID:54144-19-3

 

Joint Institutte for Nuclear Research

BERKELEY LAB

First prepared in 2002 by (Yuri Tsolakovich Oganessian), V.K. Utyonkov, Yu.V. Lobanov, F.Sh. Abdullin, A.N. Polyakov, I.V. Shirokovsky, Yu.S. Tsyganov, A.N. Mezentsev, S. Iliev, V.G. Subbotin, A.M. Sukhov, O.V. Ivanov, A.A. Voinov, K. Subotic, V.I. Zagrebaev, (M.G. Itkis) ( / JINR), K.J. Moody, J.F. Wild, M.A. Stoyer, N.J. Stoyer, C.A. Laue, D.A. Shaughnessy, J.B. Patin, and R.W. Lougheed (Lawrence Livermore National Laboratory, University of California) at the / Flerov Laboratory of Nuclear Reactions, FLNR - JINR, (Dubna), Russia. 
 
 Name derived fromThe element does not have a name yet, therefore the systematic IUPAC  name Uuo is used.

Ununoctium is pronounced as
oon-oon-OCT-i-em
  
 Candidate nameMoskowium, Mk ?
 
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Synthesis of element 118

In spring 2002, when running the experiment with the reaction 

24998Cf + 4820Ca → 294118Uuo + 31n,

with high beam dose 2.5*1019 ions of 48Ca (the experiment lasted about four months), we detected a single event of production of a superheavy nucleus, that followed a decay pattern: R → 1 →2 →SF, with energies and decay times expected for the even–even isotope 294118. In the following three years, we synthesized a series of isotopes of elements 112, 114, and 116 and determined their decay properties. These included the isotopes 290,291116, 286,287114, and 282,283112 (the daughter products of sequential -decays of the mother nuclei 295118 and 294118), which could be produced in the most probable reaction channels with the emission of two and three neutrons, respectively. From this data, one could construct the decay scenario of the -radioactive isotopes 294118, 295118 and determine the decay characteristics of their daughter nuclei.

Uuo decayFrom the decay properties of the isotopes 291116 and 290116, it followed that the above-mentioned single event, observed in the reaction 48Ca + 249Cf, refers to the formation and decay of 294118. In February 2005, we started, with higher sensitivity, the second experiment 48Ca + 249Cf, which was finished in March. Here, with the beam dose of 1.6*1019, we detected two more decay events of the isotope 294118 that completely agreed with the expected energies and half-lives of the daughter nuclei: 290116() →286114(SF/) →282112(SF). Finally, in the reaction  

24596Cm + 4820Ca → 294118Uuo + 31n,

we measured the dependencies of the production cross-sections of the isotopes of element 116 on the 48Ca beam energy (excitation functions). From this experiment, it also follows that the daughter nuclide of the -decay of nuclei with Z = 118 is the isotope of element 116 with mass 290 that was produced in the 3n-evaporation channel of the reaction 48Ca + 245Cm. Now, summing the data of the two experiments with the reaction 48Ca + 249Cf and the decay properties of the daughter products—the isotopes 290116, 286114, and 282112 — which were synthesized in the reactions 238U, 242Pu and 245Cm + 48Ca, we can show the decay properties of the heaviest nuclide 294118

Pure Appl. Chem., Vol. 78, No. 5, pp. 889–904, 2006. Yu.Ts. Oganessian "Synthesis and decay properties of superheavy elements"  Synthesis and decay properties of superheavy elements

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Microscopic Description of Super Heavy Nuclei  Microscopic Description of Super Heavy Nuclei Y. K . Gambhir , A. Bhagwat and M. Gupta
arXiv:nucl-th/0505067 v1 26 May 2005   
http://arxiv.org/pdf/nucl-th/0505067

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http://159.93.28.88/linkc/118/anno.html

ELEMENT 118: Yu.Ts. Oganessian et al., "Results from the first 249Cf + 48Ca Experiment"  RESULTS from 249Cf + 48Ca

The results of an attempt aimed at the synthesis of element 118 in the reaction 249Cf (48Ca,3n)  294118 are reported. The experiment was performed employing the Dubna Gas-Filled Recoil Separator and the U-400 heavy-ion cyclotron at FLNR (JINR, Dubna). In the course of a 2300-hour irradiation of an enriched 249Cf target (0.23 mg/cm2) with a beam of 245-MeV 48Ca ions, we accumulated a total beam dose of 25;1019 ions. We detected two events that may be attributed to the formation and decay of nuclei with Z = 118. For one event, we observed -decay chain of two correlated -decays with corresponding energies and correlation times of E1= (11.65 ±0.06) MeV, tl=255ms and E2 = (10.71 ± 0.17)MeV, t2=42.1 ms and, finally, a spontaneous fission with the sum of the kinetic energies of the fission fragments Etot = 207 MeV (TKE - 230 MeV) and tSF = 0.52 s. In the second event chain, the recoil nucleus decayed into two fission fragments with Etot =223MeV (TKE ~245 MeV) 3.16 ms later, without intervening -decays. The probabilities that these events were caused by the chance correlations of unrelated signals are negligible. Both events were observed at an excitation energy of the compound nucleus 297118 of E* = (30.0 ±2.4) MeV, close to the expected maximum of the 3n-evaporation channel. 
 
4820Ca + 24998Cf → [297118Uuo →  294118Uuo + 3 10n   and  295118Uuo + 2 10n

The relationship between the decay energy Q and decay period T shows that sequential -transitions in the first event correspond to the decay chain with Z = 118 --> 116-->114. Decay characteristics of the newly observed nuclides are compared with radioactive decay properties of the even-even isotopes with Z= 116, 114 and 112 previously produced in the reactions 244Pu; 248Cm + 48Ca and with calculations made in various nuclear models. The investigation has been performed at the Flerov Laboratory of Nuclear Reactions, JINR.
Communication of the Joint Institute for Nuclear Research. Dubna, 2002
http://flerovlab.jinr.ru/flnr/elm118.html
  

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On June 7, 1999, scientists working at the U.S. Department of Energy's Lawrence Berkeley National Laboratory announced the discovery of element 118. The scientists attempted to make element 118 by smashing krypton ions into a lead target with a machine called a cyclotron. Three atoms of element 118 were thought to have been created during 11 days of experimentation.The Lawrence Berkeley scientists, as well as other scientists at other labs, attempted to confirm the discovery of element 118. Duplicate experiments conducted at other labs failed to produce any sign of element 118. A careful re-analysis of the original data using different software also failed to find any evidence of element 118. As a result of these failures, the Lawrence Berkeley scientists retracted their claim on July 27, 2001.

Nature 418 ; 18 July 2002

For completeness, the Ninov et al . Berkeley collaboration report on the reaction

20882Pb + 8636Kr → 293118Uuo + 1n

in which three chains are observed to commence with 293118. Retraction of results appears in :

V. Ninov, K. E. Gregorich, W. Loveland, A. Ghiorso, D. C. Hoffman, D. M. Lee, H. Nitsche, W. J. Swiatecki, U. W. Kirbach, C. A. Laue, J. L. Adams, J. B. Patin, D. A. Shaughnessy, D. A. Strellis, P. A. Wilk. Editorial note: Observation of superheavy nuclei produced in the reaction of 86 Kr with 208 Pb [ Phys. Rev. Lett . 83 , 1104 (1999)], Phys. Rev. Lett. 89 , 039901 (2002).  

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APSIDIUM    Created:    

2002-09-01

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